You can press shift + esc to disable Vimperator on pages and insert to enable it again. 
This is not good solution as often times you wan to disable Vimperator on a few pages 
but still have it enabled on other pages. 
You can achieve this by configurating the ~/.vimperatorrc file.
Below is an example of disabling Vimperator on Google main, calendar, reader and tasks. 
autocmd LocationChange .*                             js modes.passAllKeys = false
autocmd LocationChange mail\\.google\\.com            js modes.passAllKeys = true
autocmd LocationChange www\\.google\\.com/calendar    js modes.passAllKeys = true
autocmd LocationChange www\\.google\\.com/reader      js modes.passAllKeys = true
autocmd LocationChange mail\\.google\\.com/tasks      js modes.passAllKeys = false
Instead of using autocmd, 
you can also use ignorekeys. 
Below is an exampel of disabling Vimperator on Yahoo and Google mail.
ignorekeys add mail.yahoo.com
ignorekeys add mail.google.com