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You can follow the steps below to create a distribution list in Outlook 2010.
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Select the Home menu button and then click the Address Book button in the "Find" group.
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Click the drop-down list below "Address Book" in the prompt and then select Contacts.
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Select the "File" menu and then click "New Entry...".
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Choose "New Contact Group" for the entry type in the prompt. Under the "Put this entry in:" drop-down list, select the destination where the distribution is to be created.
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Click OK.